Yes Event Espresso records all registrations to the database regardless of if a attendee/registrant has completed a payment. This information will then be available on the attendee list screen for an event.
You can adjust the primary email for the admin through WordPress admin –> Event Espresso –> General Settings.
Here is the changelog for the newer versions of Event Espresso:
The support post ‘Register Events Confirmation Email User data’ is closed to new replies.
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Support forum for Event Espresso 3 and Event Espresso 4.